What you're describing is called "galvanic response", I believe, and IS due to a small electrical current that is formed when different metals, such as aluminum and steel come in contact with each other. It causes corrosion to form.
The usual problems that have been reported are holes in the aluminum roof over nails or screws that were used to hold down the plywood. This problem is aggravated in areas of high humidity, which your location certainly has.
I don't know if there's anything you can do to repair your damage other than replacing the roof, but other members here may have some ideas.
- Jack
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