Hi Bruce - The exhaust fan is not there to get rid of fumes. It draws air over the heat exchanger fins behind the refrigerator which helps to cool them down. Essentially, the heat removed from the inside of the refrigerator is transferred to these fins by the action of the ammonia coolant. As the fins heat up, they lose the ability to accept additional heat from the space you want to keep cold. So, moving air across them gets rid of some of that excess heat to improve your cooling efficiency.
If you go outside and if the refrigerator fan is actually running, you can feel this air flow and heat at the vent behind the refrigerator. I say "actually running", because the fan does not start turning until the temperature at that heat exchanger reaches some threshold level (I think it's 120 degrees, but I could be wrong). So, just flipping the switch does not actually start the fan, it just "arms" it so it will run when things heat up.
Some people don't bother to turn the fan on if it's cold out. Personally, I turn it on any time the refrigerator is on. AND, if you are traveling with the refrigerator on and the top is down, the fan SHOULD be on because the air circulation behind the refrigerator is restricted.
- Jack