If you ran another duct, of course it would take some flow from other outlets, in a perfect "world" scenario, a third vent would cost some flow to the other vents, to instead of 50/50 it would be 33.3/33.3/33.3 of the air flow to the vents. however if the vent is easier flowing (closer to the AC, is an example) it could rob a more from the other vents. which would then cause you to adjust the flow, by blocking the vent a little bit, I have used some seat foam for this, or squeezing the hose closed a little bit.
I have the same problem with the overhead bedroom on my 5th, and my wife who wants arctic air to be blusteringly blowing onto her face (which is all that sticks out of the blankets, lol).
I actually bought parts to add a duct to the up front area, and will be removing from another area, (leaving the vent cover in place for looks) that seems to waste all the cooling that it could provide, because it dumps onto floor right beside the recirculation vent... Overall the same amount of air will come out of the AC, it will be just placed/routed in different places in the camper.